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1,5-Cyclooctadien(Pyridin)(Tricyclohexylphosphin)iridium(I)-Hexafluorophosphat, 99 %, Thermo Scientific Chemicals

Artikelnummer. 11369717
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Menge:
50 mg
Packungsgröße:
50 Milligramm
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11369717 50 mg 50 Milligramm
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Artikelnummer. 11369717 Lieferant Thermo Scientific Alfa Aesar Lieferanten-Nr. 042057.MF
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Verfügbar ab: 07-12-2026
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Description

CAS: 64536-78-3 | C31H50F6IrNP2 | 804.90 g/mol

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

 
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Specifications

Chemischer Name oder Material 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
CAS 64536-78-3
Schmelzpunkt 175°C (decomposition)
Summenformel C31H50F6IrNP2
MDL-Nummer MFCD00075097
Menge 50 mg
Empfindlichkeit Moisture sensitive
Synonym crabtree's catalyst, unii-816 rs2nbpn, 816 rs2nbpn, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium hexafluorophosphate, iridium i hexafluorophosphate, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium i hexafluorophosphate, tricyclohexylphosphine 1,5-cyclooctadiene pyridine iridium i hexafluorophosphate, felkin-crabtree catalyst, crabtree's catalyst mi, crabtree's catalyst hexafluorophosphate
Löslichkeitsinformationen Slightly soluble in acetone,dichloromethane,ethanol and diethyl ether; Insoluble aq. soln..
InChI-Schlüssel UJXHUUQZACSUOG-KJWGIZLLSA-N
SMILES [Ir+].C1=CC=NC=C1.F[P-](F)(F)(F)(F)F.C1C\C=C/CC\C=C/1.C1CCC(CC1)P(C1CCCCC1)C1CCCCC1
IUPAC-Name cycloocta-1,5-diene hexafluoro-λ5-phosphanuide pyridine tricyclohexylphosphane iridium
Molekulargewicht (g/mol) 804.90
PubChem CID 5702647
Formelmasse 804.89
Reinheit (%) 99%
Physikalische Form Kristallin
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