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  7. (+/-)-trans-1,2-Diaminocyclohexan, 99 %, Thermo Scientific Chemicals

(+/-)-trans-1,2-Diaminocyclohexan, 99 %, Thermo Scientific Chemicals

Artikelnummer. 11396926
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Product Code. 11396926 Supplier Thermo Scientific Alfa Aesar Supplier No. L06626.30
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Description

CAS: 1121-22-8 | C6H14N2 | 114.192 g/mol

(±)-trans-1,2-Diaminocyclohexane is employed in the synthesis of macrocyclic [3+3] hexa Schiff base. It also plays an important role in the preparation of multidentate ligands, chiral auxiliaries and chiral stationary phases. Further, it is used to prepare [2+2] macrocyclization by reacting with aliphatic dialdehydes. In addition to this, it acts as a chiral ligand, which finds application in asymmetric catalysis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Anwendungen
(^+)-trans-1,2-Diamincyclohexan wird bei der Synthese der makrocyclischen [3+3]Hexa-Schiffschen-Base eingesetzt. Es spielt auch eine wichtige Rolle bei der Herstellung von Multidentatliganden, chiralen Hilfsmitteln und chiralen stationären Phasen. Des Weiteren wird es zur Vorbereitung der [2+2]-Makrozyklisierung durch Reaktion mit aliphatischen Dialdehyden verwendet. Darüber hinaus dient es als chiraler Ligand, der bei der asymmetrischen Katalyse verwendet wird.

Löslichkeit
Mit Wasser mischbar.

Hinweise
Nicht kompatibel mit starken Oxidationsmitteln und starken Säuren.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 1121-22-8
Summenformel C6H14N2
Molekulargewicht (g/mol) 114.192
MDL-Nummer MFCD00063747
InChI-Schlüssel SSJXIUAHEKJCMH-PHDIDXHHSA-N
Synonym 1r,2r---1,2-diaminocyclohexane, 1r,2r-cyclohexane-1,2-diamine, trans-1,2-diaminocyclohexane, trans-1,2-cyclohexanediamine, trans-cyclohexane-1,2-diamine, 1r,2r-1,2-diaminocyclohexane, 1r,2r---1,2-cyclohexanediamine, 1r,2r-diaminocyclohexane, r-dach, 1r,2r-1,2-cyclohexanediamine
PubChem CID 43806
IUPAC-Name (1R,2R)-Cyclohexan-1,2-diamin
SMILES C1CCC(C(C1)N)N

Specifications

Chemischer Name oder Material (+/-)-trans-1,2-Diaminocyclohexane
Schmelzpunkt 14°C to 15°C
Dichte 0.951
Siedepunkt 89°C to 90°C (14 mmHg)
Flammpunkt 68°C (154°F)
Geruch Amine-like
Brechungsindex 1.489
Menge 250 g
UN-Nummer UN2735
Beilstein 3193807
Empfindlichkeit Air sensitive; May form a precipitate
Löslichkeitsinformationen Miscible with water.
Formelmasse 114.19
Reinheit (%) 99%
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