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  8. Benzylphenylether, 97 %, Thermo Scientific Chemicals

Benzylphenylether, 97 %, Thermo Scientific Chemicals

Product Code. 11415107
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Product Code. 11415107 Supplier Thermo Scientific Alfa Aesar Supplier No. B22539.06
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Description

CAS: 946-80-5 | C13H12O | 184.238 g/mol

Benzyl phenyl ether reacts with aluminum bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane. It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal. Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported. Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated. Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Anwendungen
Benzylphenylether reagiert mit Aluminiumbromid in Chlorbenzol-Lösung, um eine Mischung aus Phenol, O-Benzylphenol und Dichlordiphenylmethan zu ermöglichen. Als Modellverbindung in der katalytischen Chemie ist es sinnvoll, die a-O4-Etherbindung in Lignin und Kohle darzustellen. Es enthält eine schwache Etherbindung von 234 kJ/mol und gehört zu den meisten thermolabilen Verbindungen in Lignin und niedrig eingestufter Kohle. Der Einfluss von Alkalikarbonaten, häufig verwendeten Additiven bei der Biomasseumwandlung, auf die Reaktionswege von BPE in überhitztem Wasser wurde nachgewiesen. Die durch Cäsium-getauschte Heteropolysäure katalysierte Zersetzung von Benzylphenylether zu Aromaten wurde untersucht. Photo-Claisen-Umordnungen von Benzylphenylether wurden bei Kationen-getauschten Y-Zeolithen und Polyethylenen mit unterschiedlichen Kristallinitäten untersucht.

Löslichkeit
Unlöslich in Wasser.

Hinweise
Stabil unter empfohlenen Lagerbedingungen. Nicht kompatibel mit Oxidationsmitteln.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 946-80-5
Summenformel C13H12O
Molekulargewicht (g/mol) 184.238
MDL-Nummer MFCD00020660
InChI-Schlüssel BOTNYLSAWDQNEX-UHFFFAOYSA-N
Synonym benzyl phenyl ether, benzyloxy benzene, phenyl benzyl ether, benzene, phenoxymethyl, ether, benzyl phenyl, benzylphenylether, benzyloxy-benzene, benzyloxybenzene, unii-bue863n0l8, .alpha.-phenylanisole
PubChem CID 70352
IUPAC-Name Phenoxymethylbenzol
SMILES C1=CC=C(C=C1)COC2=CC=CC=C2

Specifications

Chemischer Name oder Material Benzyl phenyl ether
Schmelzpunkt 37°C to 40°C
Siedepunkt 286°C to 287°C
Flammpunkt >110°C (230°F)
Menge 5 g
Beilstein 2045713
Löslichkeitsinformationen Insoluble in water.
Formelmasse 184.24
Reinheit (%) 97%

RUO – Research Use Only

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